School of Engineering, The University of Edinburgh, King's Buildings, Mayfield Road, Edinburgh EH9 3JL, United Kingdom.
Adv Colloid Interface Sci. 2014 Apr;206:372-81. doi: 10.1016/j.cis.2013.05.002. Epub 2013 May 14.
The objective of this review is to investigate different deposition patterns from dried droplets of a range of fluids: paints, polymers and biological fluids. This includes looking at mechanisms controlling the patterns and how they can be manipulated for use in certain applications such as medical diagnostics and nanotechnology. This review introduces the fundamental properties of droplets during evaporation. These include profile evolution (constant contact angle regime (CCAR) and constant radius regime (CRR)) and the internal flow (Marangoni and Capillary flow (Deegan et al. [22])). The understanding of these processes and the basic physics behind the phenomenon are crucial to the understanding of the factors influencing the deposition patterns. It concludes with the applications that each of these fluids can be used in and how the manipulation of the deposition pattern is useful. The most commonly seen pattern is the coffee-ring deposit which can be seen frequently in real life from tea/coffee stains and in water colour painting. This is caused by an outward flow known as capillary flow which carries suspended particles out to the edge of the wetted area. Other patterns that were found were uniform, central deposits and concentric rings which are caused by inward Marangoni flow. Complex biological fluids displayed an array of different patterns which can be used to diagnose patients.
本次综述的目的在于研究一系列流体(包括油漆、聚合物和生物流体)干燥液滴的不同沉积模式。这包括研究控制这些模式的机制以及如何将其应用于特定领域,如医疗诊断和纳米技术。本综述介绍了蒸发过程中液滴的基本特性。这些特性包括轮廓演变(恒定接触角阶段(CCAR)和恒定半径阶段(CRR))和内部流动(Marangoni 流和毛细流动(Deegan 等人,[22]))。理解这些过程以及背后的基本物理现象对于理解影响沉积模式的因素至关重要。本文最后介绍了每种流体的应用以及沉积模式的操控如何带来的益处。最常见的模式是咖啡环沉积,这种现象在日常生活中很常见,例如茶/咖啡渍和水彩画。这是由向外流动的毛细流动引起的,它将悬浮颗粒带到润湿区域的边缘。还发现了其他模式,包括均匀的中心沉积和同心环,这是由向内的 Marangoni 流引起的。复杂的生物流体表现出一系列不同的模式,可用于诊断患者。