Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing, 100084, China.
Nanoscale. 2013 Jul 21;5(14):6584-8. doi: 10.1039/c3nr01877f. Epub 2013 Jun 12.
Carbon nanotubes (CNTs) are promising building blocks for nanodevices owing to their superior electrical, thermal and mechanical properties. One of the key issues for their study and application is the efficient location, transfer and manipulation of individual CNTs. In this contribution, we show that the manipulation of individual suspended CNTs has been carried out on the macroscale under low magnification, using inorganic nanoparticles (NPs) as indicators. Individual ultralong CNTs can be stretched, cut, and transferred to other substrates for further characterization. Complicated CNT structures were fabricated under optical microscopes. The inorganic NPs also facilitate the manipulation and characterization of individual CNTs under a scanning electron microscope with low magnification. Additionally, the irregular NPs deposited on suspended CNTs can also make the outer shell of the suspended CNTs display torsion or rotation around the inner shells when placed in a flow of gas, making the fabrication of CNT-NP-hybrid-based nanodevices feasible. Our results demonstrate the extraordinary capability of this manipulation technique for individual CNTs, enabled by decoration with inorganic NPs.
碳纳米管(CNTs)由于其优异的电学、热学和力学性能,是纳米器件有前途的构建块。研究和应用的关键问题之一是实现单个 CNT 的高效定位、转移和操作。在本贡献中,我们表明,使用无机纳米颗粒(NPs)作为指示剂,可以在低倍放大下对宏观悬浮 CNT 进行操纵。可以拉伸、切割单个超长 CNT,并将其转移到其他基底上进行进一步表征。在光学显微镜下制造了复杂的 CNT 结构。无机 NPs 还便于在低倍放大的扫描电子显微镜下操纵和表征单个 CNT。此外,沉积在悬浮 CNT 上的不规则 NPs 也可以使悬浮 CNT 的外壳在气体流中围绕内部壳旋转或扭转,从而使基于 CNT-NP 杂化的纳米器件的制造成为可能。我们的结果表明,通过用无机 NPs 修饰,这种操纵技术对单个 CNT 具有非凡的能力。