锂/氯膦烯配合物与亚磷酸酯取代的酮反应：获得具有新型混合价多环 P,C-配体体系的配合物。
Reaction of Li/Cl phosphinidenoid complexes with a phosphite substituted ketone: access to complexes with a novel mixed-valence polycyclic P,C-ligand system.
机构信息
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Centre of the Russian Academy of Sciences, A.E. Arbuzov Str. 8, 420088 Kazan, Russian Federation.
出版信息
Dalton Trans. 2013 Aug 7;42(29):10510-4. doi: 10.1039/c3dt50902h.
PMID:23760069
Abstract
Reaction of Li/Cl phosphinidenoid pentacarbonyltungsten(0) complexes 2a,b (R = CH(SiMe3)2, Cp*) with bifunctional phosphite-substituted ketone 3 yielded tungsten complexes 4a,b having a novel mixed-valence polycyclic P,C-cage ligand with a P–P bond. DFT calculations provide insight into an unusual product formation pathway.
摘要
Li/Cl 膦亚基五羰基钨(0)配合物 2a,b（R = CH(SiMe3)2, Cp*）与双官能膦酸酯取代的酮 3 反应生成具有新型混合价多环 P,C-笼配体和 P-P 键的钨配合物 4a,b。DFT 计算提供了对不寻常产物形成途径的深入了解。
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