Institut für Organische Chemie, Universität Stuttgart, Pfaffenwalring 55, 70569 Stuttgart, Germany.
Beilstein J Org Chem. 2013 Jun 5;9:1093-101. doi: 10.3762/bjoc.9.121. Print 2013.
The recently introduced concept of ionic liquid crystals (ILCs) with complementary ion pairs, consisting of both, mesogenic cation and anion, was extended from guanidinium sulfonates to guanidinium sulfonimides. In this preliminary study, the synthesis and mesomorphic properties of selected derivatives were described, which provide the first example of an ILC with the sulfonimide anion directly attached to the mesogenic unit.
最近引入的具有互补离子对的离子液晶(ILC)概念,由介晶阳离子和阴离子组成,已从磺酸盐扩展到磺酰亚胺。在这项初步研究中,描述了选定衍生物的合成和介晶性质,这为直接连接到介晶单元的磺酰亚胺阴离子的 ILC 提供了第一个实例。