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粘弹性介质中的次扩散摇摆棘轮:过阻尼状态下的输运优化与热力学效率

Subdiffusive rocking ratchets in viscoelastic media: transport optimization and thermodynamic efficiency in overdamped regime.

作者信息

Kharchenko Vasyl O, Goychuk Igor

机构信息

Institute of Applied Physics, 58 Petropavlovskaya str., 40030 Sumy, Ukraine and Institute for Physics and Astronomy, University of Potsdam, Karl-Liebknecht-Str. 24/25, 14476 Potsdam-Golm, Germany.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2013 May;87(5):052119. doi: 10.1103/PhysRevE.87.052119. Epub 2013 May 15.

DOI:10.1103/PhysRevE.87.052119
PMID:23767499
Abstract

We study subdiffusive overdamped Brownian ratchets periodically rocked by an external zero-mean force in viscoelastic media within the framework of a non-Markovian generalized Langevin equation approach and associated multidimensional Markovian embedding dynamics. Viscoelastic deformations of the medium caused by the transport particle are modeled by a set of auxiliary Brownian quasiparticles elastically coupled to the transport particle and characterized by a hierarchy of relaxation times which obey a fractal scaling. The most slowly relaxing deformations which cannot immediately follow to the moving particle imprint long-range memory about its previous positions and cause subdiffusion and anomalous transport on a sufficiently long time scale. This anomalous behavior is combined with normal diffusion and transport on an initial time scale of overdamped motion. Anomalously slow directed transport in a periodic ratchet potential with broken space inversion symmetry emerges due to a violation of the thermal detailed balance by a zero-mean periodic driving and is optimized with frequency of driving, its amplitude, and temperature. Such optimized anomalous transport can be low dispersive and characterized by a large generalized Peclet number. Moreover, we show that overdamped subdiffusive ratchets can sustain a substantial load and do useful work. The corresponding thermodynamic efficiency decays algebraically in time since the useful work done against a load scales sublinearly with time following to the transport particle position, but the energy pumped by an external force scales with time linearly. Nevertheless, it can be transiently appreciably high and compare well with the thermodynamical efficiency of the normal diffusion overdamped ratchets on sufficiently long temporal and spatial scales.

摘要

我们在非马尔可夫广义朗之万方程方法及相关多维马尔可夫嵌入动力学的框架内,研究了在粘弹性介质中由外部零均值力周期性驱动的次扩散过阻尼布朗棘轮。由输运粒子引起的介质粘弹性变形,通过一组与输运粒子弹性耦合的辅助布朗准粒子进行建模,这些准粒子具有服从分形标度的弛豫时间层次结构。最缓慢弛豫的变形不能立即跟随移动粒子,会留下关于其先前位置的长程记忆,并在足够长的时间尺度上导致次扩散和反常输运。这种反常行为与过阻尼运动初始时间尺度上的正常扩散和输运相结合。由于零均值周期性驱动违反了热细致平衡,在具有破缺空间反演对称性的周期性棘轮势中出现了反常缓慢的定向输运,并且这种输运可通过驱动频率、其振幅和温度进行优化。这种优化的反常输运可以是低色散的,并以大的广义佩克莱数为特征。此外,我们表明过阻尼次扩散棘轮可以承受相当大的负载并做有用功。相应的热力学效率随时间代数衰减,因为克服负载所做的有用功随输运粒子位置随时间呈次线性缩放,但外力泵入的能量随时间呈线性缩放。然而,在足够长的时间和空间尺度上,它可以瞬间相当高,并且与正常扩散过阻尼棘轮的热力学效率相当。

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