金（I）催化的炔基连接的烯酰胺的6-内型-双加水环化反应：合成1,6-二氢吡啶-2(3H)酮 - Suppr

Suppr

超能文献

Gold(I)-catalyzed 6-endo-dig hydrative cyclization of an alkyne-tethered ynamide: access to 1,6-dihydropyridin-2(3H)ones.

作者信息

Ghosh Nayan, Nayak Sanatan, Sahoo Akhila K

机构信息

School of Chemistry, University of Hyderabad, Hyderabad-500046, India.

出版信息

Chemistry. 2013 Jul 15;19(29):9428-33. doi: 10.1002/chem.201301599. Epub 2013 Jun 20.

DOI:10.1002/chem.201301599

PMID:23788463

Abstract

摘要

相似文献

Gold(I)-catalyzed 6-endo-dig hydrative cyclization of an alkyne-tethered ynamide: access to 1,6-dihydropyridin-2(3H)ones.金（I）催化的炔基连接的烯酰胺的6-内型-双加水环化反应：合成1,6-二氢吡啶-2(3H)酮

Chemistry. 2013 Jul 15;19(29):9428-33. doi: 10.1002/chem.201301599. Epub 2013 Jun 20.

A 6--dig Thiolative Cyclization of Yne-Ynamides: Access to Thiodihydropyridin-2-ones.炔基烯酰胺的六步硫醇化环化反应：合成硫代二氢吡啶-2-酮

Org Lett. 2022 Nov 18;24(45):8289-8294. doi: 10.1021/acs.orglett.2c03225. Epub 2022 Nov 4.

Gold-catalyzed cyclization and cycloisomerization of yne-tethered ynamide: the significance of a masked enol-equivalent of an amide.金催化的炔基连接的烯炔酰胺的环化和环异构化：酰胺的掩蔽烯醇等效体的意义。

Org Biomol Chem. 2016 Jan 21;14(3):803-7. doi: 10.1039/c5ob02262b. Epub 2015 Nov 27.

Alkyne Versus Ynamide Reactivity: Regioselective Radical Cyclization of Yne-Ynamides.炔烃与烯炔酰胺的反应活性：烯炔酰胺的区域选择性自由基环化反应

Angew Chem Int Ed Engl. 2019 Feb 18;58(8):2289-2294. doi: 10.1002/anie.201811947. Epub 2019 Jan 18.

Gold(i)-catalyzed 6-endo-dig azide-yne cyclization: efficient access to 2H-1,3-oxazines.金（I）催化的6-内型-双氮杂环丙烷-炔环化反应：高效合成2H-1,3-恶嗪的方法

Chem Commun (Camb). 2017 Jan 5;53(4):736-739. doi: 10.1039/c6cc08397h.

Enantioselective Gold(I)-Catalyzed Hydrative Cyclizations of -Propargyl-ynamides into 3,6-Dihydropyridinones.对映选择性金（I）催化的炔丙基-烯酰胺水合环化反应生成3,6-二氢吡啶酮

Org Lett. 2019 Dec 6;21(23):9281-9285. doi: 10.1021/acs.orglett.9b02644. Epub 2019 Nov 25.

Dimethyl Sulfoxide and N-Iodosuccinimide Promoted 5-exo-dig Oxidative Cyclization of Yne-Tethered Ynamide: Access to Pyrrolidones and Spiro-pyrrolidones.二甲基亚砜和 N-碘代丁二酰亚胺促进炔基连接的炔酰胺的 5-exo- 氧化环化：得到吡咯烷酮和螺-吡咯烷酮。

Org Lett. 2016 Jul 1;18(13):3066-9. doi: 10.1021/acs.orglett.6b01149. Epub 2016 Jun 22.

p-TsOH Promoted Au(I)-Catalyzed Consecutive Endo Cyclization of Yne-Tethered Ynamide: Access to Benzofused Dihydroisoquinolones.对甲苯磺酸促进金（I）催化的炔基连接的烯酰胺的连续内型环化反应：合成苯并稠合二氢异喹啉酮。

Org Lett. 2015 Nov 20;17(22):5662-5. doi: 10.1021/acs.orglett.5b02946. Epub 2015 Nov 2.

Umpolung Reactivity of Ynamides: An Unconventional [1,3]-Sulfonyl and [1,5]-Sulfinyl Migration Cascade.烯酰胺的极性反转反应性：一种非常规的[1,3]-磺酰基和[1,5]-亚磺酰基迁移串联反应

Angew Chem Int Ed Engl. 2019 Feb 18;58(8):2365-2370. doi: 10.1002/anie.201813143. Epub 2019 Jan 21.

Gold-catalyzed hydrative carbocyclization of 1,5- and 1,6-diyn-3-ones via an oxygen transfer process.通过氧转移过程实现金催化的1,5-和1,6-二炔-3-酮的水合碳环化反应。

J Org Chem. 2008 Nov 7;73(21):8479-83. doi: 10.1021/jo801753g. Epub 2008 Oct 4.

引用本文的文献

Enantioselective functionalization of unactivated C(sp)-H bonds through copper-catalyzed diyne cyclization by kinetic resolution.通过动力学拆分的铜催化二炔环化实现未活化C(sp) - H键的对映选择性官能团化。

Nat Commun. 2024 Mar 12;15(1):2232. doi: 10.1038/s41467-024-46288-7.

Straightforward Synthesis of Indenes by Gold-Catalyzed Intramolecular Hydroalkylation of Ynamides.通过金催化的烯酰胺分子内氢烷基化直接合成茚。

ACS Org Inorg Au. 2021 Oct 14;2(1):53-58. doi: 10.1021/acsorginorgau.1c00021. eCollection 2022 Feb 2.

Asymmetric synthesis with ynamides: unique reaction control, chemical diversity and applications.炔酰胺的不对称合成：独特的反应控制、化学多样性及应用。

Chem Soc Rev. 2020 Dec 7;49(23):8543-8583. doi: 10.1039/d0cs00769b. Epub 2020 Oct 19.

Harnessing the Electrophilicity of Keteniminium Ions: A Simple and Straightforward Entry to Tetrahydropyridines and Piperidines from Ynamides.利用烯酮亚胺离子的亲电性：一种从烯酰胺简便直接合成四氢吡啶和哌啶的方法。

Angew Chem Int Ed Engl. 2016 Mar 24;55(14):4547-51. doi: 10.1002/anie.201510729. Epub 2016 Mar 2.

1,2-N-migration in a gold-catalysed synthesis of functionalised indenes by the 1,1-carboalkoxylation of ynamides.通过烯酰胺的1,1-碳烷氧基化反应在金催化合成官能化茚过程中的1,2-N迁移

Chemistry. 2014 Jun 10;20(24):7262-6. doi: 10.1002/chem.201403040. Epub 2014 May 14.

Ynamides in ring forming transformations.酰胺在成环转化中的应用。

Acc Chem Res. 2014 Feb 18;47(2):560-78. doi: 10.1021/ar400193g. Epub 2013 Oct 28.

文献AI研究员

20分钟写一篇综述，助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型，支持多种主流文档格式。

立即体验