Institut de Science et d'Ingénierie Supramoléculaires (ISIS), Université de Strasbourg, 8 allée Gaspard Monge, 67000, Strasbourg, France.
Chem Soc Rev. 2013 Oct 7;42(19):7881-99. doi: 10.1039/c3cs60061k. Epub 2013 Jun 24.
Metallosupramolecular grid complexes (hereafter referred to as metallogrids) are well-defined oligonuclear metal ion complexes involving essentially planar arrays of the metal ions sited at the points of intersection of square or rectangular metallogrids and possess a variety of interesting optical, electronic, magnetic and supramolecular properties. Herein I aim to give the reader an overview of the synthesis, properties and potential for a variety of high-tech applications of metallogrids.
金属超分子网格配合物(以下简称金属网格)是指由金属离子组成的具有明确结构的寡核配合物,这些金属离子位于正方形或长方形金属网格的交点处,形成基本平面排列,具有多种有趣的光学、电子、磁性和超分子性质。在此,我旨在为读者概述金属网格的合成、性质以及在各种高科技应用方面的潜力。