Suppr超能文献

2-(4-甲基吡啶-2-基)-4',4',6',6'-四(吡咯烷-1-基)-1H,2H-螺[萘并-[1,2-e][1,3,2]氧氮杂膦-3,2'-[1,3,5,2,4,6]三氮杂三膦]

2-(4-Methyl-pyridin-2-yl)-4',4',6',6'-tetra-kis-(pyrrolidin-1-yl)-1H,2H-spiro-[naphtho-[1,2-e][1,3,2]oxaza-phosphinine-3,2'-[1,3,5,2,4,6]tri-aza-triphosphinine].

作者信息

Işıklan Muhammet, Sonkaya Omer, Hökelek Tuncer

机构信息

Department of Chemistry, Kırıkkale University, 71450 Kırıkkale, Turkey.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 May 31;69(Pt 6):o994-5. doi: 10.1107/S1600536813014220. Print 2013 Jun 1.

Abstract

In the title spiro-phosphazene derivative, C33H46N9OP3, the phosphazene and six-membered N/O rings are in flattened chair and twisted-boat conformations, respectively. The naphthalene ring system and the pyridine ring are oriented at a dihedral angle of 41.82 (4)°. In the crystal, weak C-H⋯O hydrogen bonds link the mol-ecules related by translation along the a axis into chains. C-H⋯π inter-actions aggregate these chains into layers parallel to the ab plane.

摘要

在标题螺环磷腈衍生物C33H46N9OP3中,磷腈和六元N/O环分别处于扁平椅式和扭曲船式构象。萘环体系和吡啶环以41.82 (4)°的二面角取向。在晶体中,弱的C-H⋯O氢键将沿a轴平移相关的分子连接成链。C-H⋯π相互作用将这些链聚集形成平行于ab平面的层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76b4/3685126/36598a09cd82/e-69-0o994-fig1.jpg

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验