Işıklan Muhammet, Sonkaya Omer, Hökelek Tuncer
Department of Chemistry, Kırıkkale University, 71450 Kırıkkale, Turkey.
Acta Crystallogr Sect E Struct Rep Online. 2013 May 31;69(Pt 6):o994-5. doi: 10.1107/S1600536813014220. Print 2013 Jun 1.
In the title spiro-phosphazene derivative, C33H46N9OP3, the phosphazene and six-membered N/O rings are in flattened chair and twisted-boat conformations, respectively. The naphthalene ring system and the pyridine ring are oriented at a dihedral angle of 41.82 (4)°. In the crystal, weak C-H⋯O hydrogen bonds link the mol-ecules related by translation along the a axis into chains. C-H⋯π inter-actions aggregate these chains into layers parallel to the ab plane.
在标题螺环磷腈衍生物C33H46N9OP3中,磷腈和六元N/O环分别处于扁平椅式和扭曲船式构象。萘环体系和吡啶环以41.82 (4)°的二面角取向。在晶体中,弱的C-H⋯O氢键将沿a轴平移相关的分子连接成链。C-H⋯π相互作用将这些链聚集形成平行于ab平面的层。