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[唐山大气气溶胶颗粒中的水溶性无机盐]

[Water-soluble inorganic salts in ambient aerosol particles in Tangshan].

作者信息

Miao Hong-Yan, Wen Tian-Xue, Wang Li, Li Xing-Ru, Wang Yue-Si

机构信息

State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China.

出版信息

Huan Jing Ke Xue. 2013 Apr;34(4):1225-31.

Abstract

To investigate the levels, seasonal variation and size distributions of water soluble inorganic components, samples were collected with an Andersen cascade sampler in Tangshan from Sep. 2010 to Aug. 2011, and were analyzed by IC. The results showed that the secondary inorganic components (SO4(2-), NO3(-) and NH4(+)) were the major contributors to PM9 and PM2.1, accounting for 68% and 77% of the total water soluble salts in PM9 and PM2.1, respectively. The total concentrations of these three ions in spring, summer, autumn, and winter were 35.0, 84.7, 67.3 and 61.6 microg x m(-3) in PM9, and 23.2, 64.8, 52.7 and 49.6 microg x m(-3) in PM2.1. About 70%, 75% and 94% of SO4(2-), NO3(-) and NH4(+) were found in the fine mode of aerosol, respectively. Ca2+ and Mg2+ were unimodal and mostly concentrated in the coarse mode. Those results indicated that the pollution caused by atmospheric particles is serious in Tangshan. It is urgent to control the anthropogenic emissions sources, such as vehicle emission, coal and biomass burning. Meanwhile, it is necessary to strengthen the greening and reinforce the management of the road construction.

摘要

为研究水溶性无机成分的含量、季节变化及粒径分布,于2010年9月至2011年8月在唐山用安德森分级采样器采集样品,并采用离子色谱法进行分析。结果表明,二次无机成分(SO4(2-)、NO3(-)和NH4(+))是PM9和PM2.1的主要贡献者,分别占PM9和PM2.1中总水溶性盐的68%和77%。这三种离子在春季、夏季、秋季和冬季的总浓度在PM9中分别为35.0、84.7、67.3和61.6μg x m(-3),在PM2.1中分别为23.2、64.8、52.7和49.6μg x m(-3)。分别约70%、75%和94%的SO4(2-)、NO3(-)和NH4(+)存在于气溶胶的细模态中。Ca2+和Mg2+呈单峰分布,且大多集中在粗模态中。这些结果表明唐山大气颗粒物污染严重。迫切需要控制人为排放源,如机动车排放、煤炭和生物质燃烧。同时,有必要加强绿化并强化道路建设管理。

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