Department of Environmental Science, Babasaheb Bhimrao Ambedkar University, Rai Bareilly Road, Lucknow, India.
Int J Phytoremediation. 2013;15(8):801-13. doi: 10.1080/15226514.2012.735290.
The present study reports the influence of different factors on the sorption of Pb and Cd by Nostoc muscorum. The results showed that extent of Pb and Cd removal by N. muscorum cells increased with increasing biosorbent dose, but exhibited decline in the adsorption capacity. The maximum sorption of Cd (85.2%) and Pb (93.3%) was achieved at 60 and 80 microg/ml concentrations of respective metal, within 30 and 15 min, respectively. The result revealed that optimum biosorption of Pb and Cd occurred at pH 5 and 6, respectively, at 40 degrees C temperature. Presence of binary metals (both Pb and Cd) in a solution showed that the presence of one metal ion resulted into decreased sorption of other metal ion. The presence of Ca and EDTA showed significant decrease in the sorption of Pb and Cd, while other anions and cations did not show significant effect on the biosorption of both the metals. Maximum desorption of Pb and Cd was achieved in the presence of EDTA and HNO3, respectively. Results also showed that the test biosorbent could be repeatedly used up to six biosorption/desorption cycles without significant loss of its initial metal adsorption capacity.
本研究报告了不同因素对地木耳吸附 Pb 和 Cd 的影响。结果表明,地木耳细胞对 Pb 和 Cd 的去除程度随生物吸附剂剂量的增加而增加,但吸附容量下降。在各自金属浓度为 60 和 80μg/ml、30 和 15min 时,Cd(85.2%)和 Pb(93.3%)的最大吸附率分别达到。结果表明,Pb 和 Cd 的最佳生物吸附分别发生在 pH 值为 5 和 6、40°C 的温度下。溶液中存在二元金属(Pb 和 Cd)表明,一种金属离子的存在导致其他金属离子的吸附减少。Ca 和 EDTA 的存在显著降低了 Pb 和 Cd 的吸附,而其他阴离子和阳离子对两种金属的生物吸附没有显著影响。在 EDTA 和 HNO3 的存在下,Pb 和 Cd 的最大解吸率达到。结果还表明,测试生物吸附剂在六次吸附/解吸循环中可以重复使用,而不会显著损失其初始金属吸附能力。