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利用 Desulfovibrio sp. CMX 从螯合洗涤溶液中去除硫酸盐以去除 NO。

Sulfate removal by Desulfovibrio sp. CMX in chelate scrubbing solutions for NO removal.

机构信息

Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Linggong Road 2, Dalian 116024, PR China.

出版信息

Bioresour Technol. 2013 Sep;143:455-60. doi: 10.1016/j.biortech.2013.06.037. Epub 2013 Jun 20.

Abstract

To study the effects of Fe chelate solution and nitrosyl-complex (Fe(II)EDTA-NO), which might be introduced in the simultaneous biodesulfurization and denitrification process, on the sulfate removal process, a sulfate reducing bacteria Desulfovibrio sp. CMX was investigated for its sulfate removal capacity in the presence of Fe chelate additives and Fe(II)EDTA-NO. Meanwhile, Fe(II)EDTA-NO reduction was also investigated. The addition of Fe(II)EDTA and Fe(III)EDTA could stimulate the sulfate reduction performance. Although Fe(II)EDTA-NO could inhibit the strain, CMX could survive by consuming lactate and recover its sulfate reducing activity after Fe(II)EDTA-NO removed. Sulfate reduction could be enhanced in higher Fe(II)EDTA-NO concentrations (2 and 4 mM) by lactate applied at the middle stage of the experiment, and 72.2% and 62.6% sulfate were removed in 182 h, respectively. In this study, above 90% Fe(II)EDTA-NO (0.25-4 mM) was removed less than 60 h, which was much faster than sulfate reduction.

摘要

为研究可能在同时生物脱硫和反硝化过程中引入的螯合铁溶液和亚硝酰基配合物(Fe(II)EDTA-NO)对硫酸盐去除过程的影响,考察了硫酸盐还原菌 Desulfovibrio sp. CMX 在添加螯合铁添加剂和 Fe(II)EDTA-NO 时的硫酸盐去除能力。同时,还研究了 Fe(II)EDTA-NO 的还原情况。添加 Fe(II)EDTA 和 Fe(III)EDTA 可以刺激硫酸盐还原性能。尽管 Fe(II)EDTA-NO 可以抑制该菌株,但 CMX 可以通过消耗乳酸盐存活,并在 Fe(II)EDTA-NO 去除后恢复其硫酸盐还原活性。在实验的中期添加乳酸盐可以在较高的 Fe(II)EDTA-NO 浓度(2 和 4 mM)下增强硫酸盐还原,分别在 182 h 内去除了 72.2%和 62.6%的硫酸盐。在本研究中,不到 60 h 内去除了超过 90%的 Fe(II)EDTA-NO(0.25-4 mM),这比硫酸盐还原快得多。

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