Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (MOE), Department of Chemistry, Tsinghua University, Beijing 100084, China.
Chem Commun (Camb). 2013 Aug 18;49(64):7153-5. doi: 10.1039/c3cc43415j.
We report herein the occurrence of a positive homotropic allosteric binding effect of two macrocyclic azacalixpyridines. This effect was firstly found to be crucial in the formation and stabilization of ultra-small silver nanoparticles.
我们在此报告了两个大环氮杂杯[4]吡啶发生正同变变构结合效应的情况。首次发现该效应对超小银纳米粒子的形成和稳定起到了关键作用。
