由一对简单配体同时自组装成[2]轮烷、三叶结和司各脱链环。
Simultaneous self-assembly of a [2]catenane, a trefoil knot, and a Solomon link from a simple pair of ligands.
机构信息
Centre for Science and Engineering, New York University, Abu Dhabi (NYUAD) (United Aarab Emirates, UAE).
出版信息
Angew Chem Int Ed Engl. 2013 Sep 16;52(38):9956-60. doi: 10.1002/anie.201302425. Epub 2013 Jul 5.
PMID:23832610
Abstract
A topological triptych: Three molecular links, a [2]catenane, a trefoil knot, and a Solomon link, were obtained in one pot through the self-assembly of two simple ligands in the presence of Zn(II). The approach relied on dynamic covalent chemistry and metal templation.
摘要
拓扑三联画
三种分子链接，一个[2]轮烷、三叶结和司各脱环，通过在 Zn(II)存在下两个简单配体的自组装一锅法得到。该方法依赖于动态共价化学和金属模板。
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