Institute of Organic Chemistry, University of Zurich, Winterthurerstrasse 190, 8057, Zurich, Switzerland.
Chem Commun (Camb). 2013 Aug 21;49(65):7204-6. doi: 10.1039/c3cc41476k.
Five-fold symmetric substituted corannulene derivatives that display liquid-crystalline behavior and organogelation properties were prepared by coupling of N-azidoethyl long-chain fatty acid amides to sym-pentabutynyl corannulenes via dipolar cycloaddition chemistry.
通过偶极环加成化学反应，将 N-叠氮乙基长链脂肪酸酰胺与对称-五丁炔基苝连接，制备了具有液晶行为和有机凝胶化性质的五重对称取代的corannulene 衍生物。
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