Sym-(CH2X)5-corannulenes：具有功能基团和生物缀合侧链的分子五足体。
Sym-(CH2X)5-corannulenes: molecular pentapods displaying functional group and bioconjugate appendages.
机构信息
Organic Chemistry Institute, University of Zurich, Winterthurerstrasse 190, 8057 Zurich, Switzerland.
出版信息
Org Biomol Chem. 2012 Aug 14;10(30):5799-802. doi: 10.1039/c2ob25503k. Epub 2012 Apr 30.
PMID:22544281
Abstract
Pentapodal ω-functional derivatives of corannulene have been synthesized from sym-pentachlorocorannulene by iron-catalyzed aryl-alkyl cross coupling reactions. Click chemistry gives access to pentapods with bioconjugate appendages.
摘要
五足形 ω-功能化薁衍生物已通过铁催化的芳基-烷基交叉偶联反应从对称五氯薁合成。点击化学可获得带有生物缀合侧基的五足形。
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