Analysis of the hydration process and rotational dynamics of water in a Nafion membrane studied by 1H NMR spectroscopy.

(1)H NMR spectroscopy is employed to reveal the hydration process of a Nafion membrane by measuring both the chemical shift and the spin-lattice relaxation time. In a former study, the hydration process was suggested to comprise two steps: the molecular adsorption of water on the sulfonic acid groups and wetting with liquid water. The present study has revealed the first step can further be divided into two steps. By introducing a new experimental technique, the quantitatively reliable NMR measurements of protons ((1)H) of water involved in the polymer membrane are realized. In addition, a new analytical procedure is developed using a reciprocal concentration on a saturation-adsorption model, and the hydration is clearly revealed to have three individual steps. Both the chemical shift and the relaxation time plots against the reciprocal concentration exhibit three linear parts with apparently different slopes. Of great interest is that the initial hydration is divided into two stages: the first hydration is a very strong adsorption of water probably on the hydroxyl group of the sulfonic acid group, and the second one is a relatively weak adsorption on another site of the sulfonic acid group. The third hydration is readily assigned to excess bulk (liquid-like) water as expected. These adsorption processes are readily correlated with the rotational motion of water by converting the spin-lattice relaxation time to the rotational correlation time.