Nigro Biagio, Grimaldi Claudio, Ryser Peter, Varrato Francesco, Foffi Giuseppe, Lu Peter J
LPM, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland.
Phys Rev E Stat Nonlin Soft Matter Phys. 2013 Jun;87(6):062312. doi: 10.1103/PhysRevE.87.062312. Epub 2013 Jun 19.
We show that the formation of a gel by conducting colloidal particles leads to a dramatic enhancement in bulk conductivity, due to interparticle electron tunneling, combining predictions from molecular-dynamics simulations with structural measurements in an experimental colloid system. Our results show how colloidal gelation can be used as a general route to huge enhancements of conductivity, and suggest a feasible way for developing cheap materials with novel properties and low metal content.
我们表明,通过传导性胶体颗粒形成凝胶会导致整体电导率显著提高,这是由于颗粒间电子隧穿,我们将分子动力学模拟的预测与实验胶体系统中的结构测量相结合得出此结论。我们的结果表明了胶体凝胶化如何可作为大幅提高电导率的通用途径,并为开发具有新颖特性和低金属含量的廉价材料提出了一种可行方法。