Department of Chemical and Biomolecular Engineering, Yonsei University, 262 Seongsanno, Seodaemun-gu, Seoul 120-749, South Korea.
Adv Mater. 2013 Sep 20;25(35):4893-7. doi: 10.1002/adma.201302226. Epub 2013 Jul 15.
Hierarchical nanostructures of TiO2 nanosheets on SnO2 nanotubes (SNT@TNS) are uniformly dispersed in an organized mesoporous (OM) TiO2 film with large pores, high porosity, and good interconnectivity. The solid-state dye sensitized solar cells (ssDSSCs) fabricated with 10 wt% SNT@TNS dispersed in a OM-TiO2 film show an energy conversion efficiency of 7.7% at 100 mW cm(-2) , which is one of the highest values for N719-based ssDSSCs and much larger than that of a randomly oriented TiO2 nanoparticles-based cell (4.0%).
TiO2 纳米片在 SnO2 纳米管(SNT@TNS)上的分级纳米结构均匀分散在具有大孔、高孔隙率和良好互连性的有序介孔(OM)TiO2 薄膜中。在 OM-TiO2 薄膜中分散有 10wt% SNT@TNS 的固态染料敏化太阳能电池(ssDSSC)在 100mWcm(-2) 下的能量转换效率为 7.7%,这是基于 N719 的 ssDSSC 的最高值之一,远高于随机取向 TiO2 纳米粒子基电池(4.0%)的能量转换效率。