[Li+@C60](PF6(-)) 在有机溶剂中的离子电导率及其电化学还原为 Li+@C60(·-)。
Ionic conductivity of [Li+@C60](PF6(-)) in organic solvents and its electrochemical reduction to Li+@C60(·-).
机构信息
Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
出版信息
Chem Commun (Camb). 2013 Aug 28;49(67):7376-8. doi: 10.1039/c3cc43901a.
PMID:23864123
Abstract
The ionic conductivity of Li(+)@C60 was measured in o-dichlorobenzene, and found to be higher than that of TBA(+)PF6(-). Electrochemical reduction of Li(+)@C60 without any supporting electrolyte gave the monovalent radical anion Li(+)@C60˙(-), as confirmed by the characteristic ESR signal and NIR absorption band.
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