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Zn- and Co-based layered double hydroxides: prediction of the a parameter from the fraction of trivalent cations and vice versa.

作者信息

Richardson Ian G

机构信息

School of Civil Engineering, University of Leeds, LS2 9JT Leeds, England.

出版信息

Acta Crystallogr B Struct Sci Cryst Eng Mater. 2013 Aug;69(Pt 4):414-7. doi: 10.1107/S2052519213017545. Epub 2013 Jul 18.

DOI:10.1107/S2052519213017545
PMID:23873067
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3768341/
Abstract

A recently proposed method to calculate the a parameter of the unit cell of layered double hydroxides from the fraction of trivalent cations is extended to Zn- and Co-based phases. It is shown to be useful as a sanity test for extant and future structure determinations and computer-simulation studies.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b80/3768341/9a0561f0a5d2/b-69-00414-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b80/3768341/0e32370add14/b-69-00414-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b80/3768341/a42d638a9546/b-69-00414-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b80/3768341/9a0561f0a5d2/b-69-00414-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b80/3768341/0e32370add14/b-69-00414-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b80/3768341/a42d638a9546/b-69-00414-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2b80/3768341/9a0561f0a5d2/b-69-00414-fig3.jpg

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本文引用的文献

1
The importance of proper crystal-chemical and geometrical reasoning demonstrated using layered single and double hydroxides.利用层状单氢氧化物和双氢氧化物证明了适当的晶体化学和几何推理的重要性。
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2013 Apr;69(Pt 2):150-62. doi: 10.1107/S205251921300376X. Epub 2013 Feb 26.
2
Conservation of order, disorder, and "crystallinity" during anion-exchange reactions among layered double hydroxides (LDHs) of Zn with Al.锌与铝的层状双氢氧化物（LDHs）之间阴离子交换反应过程中有序性、无序性和“结晶度”的守恒。
J Phys Chem B. 2007 Apr 5;111(13):3411-8. doi: 10.1021/jp0684170. Epub 2007 Mar 9.
3
Order and disorder among the layered double hydroxides: combined Rietveld and DIFFaX approach.
层状双氢氧化物中的有序与无序：Rietveld方法与DIFFaX方法相结合
Acta Crystallogr B. 2007 Apr;63(Pt 2):243-50. doi: 10.1107/S010876810700122X. Epub 2007 Mar 16.
4
Spectroscopic investigation of Ni speciation in hardened cement paste.硬化水泥浆体中镍形态的光谱研究。
Environ Sci Technol. 2006 Apr 1;40(7):2275-82. doi: 10.1021/es052240q.
5
Synthesis, anion exchange, and delamination of Co-Al layered double hydroxide: assembly of the exfoliated nanosheet/polyanion composite films and magneto-optical studies.钴铝层状双氢氧化物的合成、阴离子交换及分层：剥离纳米片/聚阴离子复合膜的组装及磁光研究
J Am Chem Soc. 2006 Apr 12;128(14):4872-80. doi: 10.1021/ja0584471.
6
Vegard's law.维加德定律。
Phys Rev A. 1991 Mar 15;43(6):3161-3164. doi: 10.1103/physreva.43.3161.