Department of Chemical and Biological Engineering, Princeton University, Princeton, New Jersey 08544, United States.
Langmuir. 2013 Aug 6;29(31):9918-34. doi: 10.1021/la4011967. Epub 2013 Jul 22.
Water emerging from ∼100 μm pores into millimeter-size gas flow channels forms drops that grow and become slugs which span the flow channel. Flowing gas causes the slugs to detach and move down the channel. The effect of channel geometry, surface wettability, and gravity on the formation and motion of water slugs has been analyzed using high-speed video images of the drops and differential pressure-time traces. Drops grow and appear, assuming a sequence of shapes that minimize the total interfacial energy of the gas-liquid and liquid-solid interfaces. The drops are initially spherical caps centered on the pore (the liquid contacts one wall). Above a certain size, the drops move to the corner, forming "corner drops" (the liquid contacts two walls). Corner drops grow across the channel, evolving into partial liquid bridges (drops confined by three walls), and finally the drops span the channel cross-section forming slugs (contacting all four walls). Smaller slugs are formed in channels with hydrophobic walls than in channels with hydrophilic walls. Smaller slugs are formed in channels with curved walls than in square or rectangular channels. Slugs move when the differential gas pressure overcomes the force to move the advancing and receding gas-liquid-solid contact lines of the slugs. Residual water left behind in corners by moving slugs reduces the barriers for drops to form slugs, causing the steady-state slug volumes to be smaller than those seen at start-up in dry channels.
水从 ∼100 μm 的孔中进入毫米级的气体流动通道形成液滴,这些液滴会生长并变成跨越流动通道的弹状液滴。流动的气体导致弹状液滴脱离并沿通道向下移动。通过高速摄像图像和差压-时间迹线分析了通道几何形状、表面润湿性和重力对水弹形成和运动的影响。液滴生长并呈现出一系列形状,这些形状使气-液和液-固界面的总界面能最小化。液滴最初是中心位于孔上的球形帽(液体接触一个壁面)。在达到一定大小后,液滴移动到角落,形成“角状液滴”(液体接触两个壁面)。角状液滴在通道中生长,演变成部分液体桥(被三个壁面限制的液滴),最终液滴跨越通道横截面形成弹状液滴(与所有四个壁面接触)。疏水壁面通道中形成的弹状液滴比亲水壁面通道中的小。弯曲壁面通道中形成的弹状液滴比方形或矩形通道中的小。当压差克服推动和后退的弹状气-液-固接触线的力时,弹状液滴就会移动。移动的弹状液滴在角落留下的残留水会降低液滴形成弹状液滴的障碍,导致稳定状态下的弹状液滴体积比在干燥通道中启动时看到的要小。