具有稳定电化学性能和可调带隙的修饰硼亚酞菁。
Modified boron subphthalocyanines with stable electrochemistry and tuneable bandgaps.
机构信息
Department of Chemical Engineering and Applied Chemistry, 200 College St., Toronto, Ontario, CanadaM5S3E5.
出版信息
Dalton Trans. 2013 Sep 28;42(36):13145-50. doi: 10.1039/c3dt50615k. Epub 2013 Jul 24.
PMID:23880986
Abstract
The synthesis of boron subphthalocyanines (BsubPc) from modified phthalonitriles is reported. The BsubPcs have intense red-shifted absorption compared to normal BsubPcs and readily tuneable optoelectronic properties including enhanced electrochemical stability and the presence of up to two reversible electrochemical reductions.
摘要
报道了从改性邻苯二甲腈合成硼subphthalocyanines（BsubPc）。与普通 BsubPc 相比，BsubPcs 的吸收有明显的红移，而且其光电性能也容易调节，包括增强的电化学稳定性和存在两个以上的可逆电化学还原。
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