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Two polymorphs of tris(ethylenediamine)cobalt(III) tetrathioantimonate(V).

作者信息

Wang Ming-Feng, Yue Cheng-Yang, Yuan Zhuang-Dong, Lei Xiao-Wu

机构信息

Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, Shandong 273155, People's Republic of China.

出版信息

Acta Crystallogr C. 2013 Aug;69(Pt 8):855-8. doi: 10.1107/S0108270113017277. Epub 2013 Jul 20.

DOI:10.1107/S0108270113017277
PMID:23907875
Abstract

Details of the structures of two polymorphs of tris(ethylenediamine)cobalt(III) tetrathioantimonate(V), [Co(C₂H₈N₂)₃][SbS₄], are reported. The first polymorph crystallizes in the orthorhombic space group Pna2₁, whereas the second polymorph belongs to the tetragonal space group P4₂bc. Both structures contain octahedral [Co(en)₃]³⁺ cations (en is ethylenediamine) and tetrahedral [SbS₄]³⁻ anions, which are interconnected via various N-H∙∙∙S hydrogen bonds to form two different types of three-dimensional network.

摘要

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