路易斯碱稳定的母体砷硼烷H2AsBH2⋅NMe3
The Lewis Base Stabilized Parent Arsanylborane H2AsBH2⋅NMe3.
作者信息
Marquardt Christian, Adolf Ariane, Stauber Andreas, Bodensteiner Michael, Virovets Alexander V, Timoshkin Alexey Y, Scheer Manfred
机构信息
Institut für Anorganische Chemie, Universität Regensburg, 93040 Regensburg (Germany), Fax: (+49) 941-9434439.
出版信息
Chemistry. 2013 Sep 2;19(36):11887-91. doi: 10.1002/chem.201302110. Epub 2013 Jul 31.
Exclusively hydrogen-substituted arsanylboranes: The synthesis of the unprecedented Lewis base stabilized monomeric parent compound of the arsanylborane H2AsBH2⋅NMe3 was achieved in a one-pot reaction in high yield and purity. The analogous phosphanylborane was synthesized in a similar manner. A series of different reactions was performed on H2AsBH2⋅NMe3 to show its broad reactivity pattern.
仅含氢取代的胂硼烷
通过一锅法反应以高收率和纯度实现了前所未有的由路易斯碱稳定的胂硼烷H2AsBH2·NMe3单体母体化合物的合成。类似的膦硼烷也以类似方式合成。对H2AsBH2·NMe3进行了一系列不同反应，以展示其广泛的反应模式。
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