State Key Laboratory of Chemical Resource Engineering & Key Laboratory of Carbon Fiber and Functional Polymer, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China.
Chem Commun (Camb). 2013 Sep 21;49(73):8093-5. doi: 10.1039/c3cc44580a. Epub 2013 Aug 5.
We develop a facile method to immobilize cucurbituril on silicon substrates through photochemical reaction with azido groups. Combining photolithography and the competitive molecular recognition between CB[7] and acridine orange base or 1-adamantanecarboxylic acid, a patterned surface with reversible fluorescence emission can be obtained.
我们开发了一种简便的方法,通过与叠氮基团的光化学反应将葫芦脲固定在硅基底上。通过光刻和 CB[7]与吖啶橙碱基或 1-金刚烷羧酸之间的竞争分子识别相结合,可以得到具有可逆荧光发射的图案化表面。