Department of Chemistry and Pharmacy, and Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen, Germany.
Philos Trans A Math Phys Eng Sci. 2013 Aug 5;371(1998):20120490. doi: 10.1098/rsta.2012.0490. Print 2013 Sep 13.
In this paper, we report on the design, redox potentials, excited state energies and radical ion pair state energies in electron donor-acceptor conjugates comprising the electron-donating π-extended tetrathiafulvalene and several electron-accepting fullerenes. To this end, we contrast an empty fullerene, that is, C₆₀, with two endohedral metallofullerenes, that is, open-shell La@C₈₂ and closed-shell La₂@C₈₀, in terms of charge separation and charge recombination dynamics.
在本文中，我们报告了由供电子的扩展型四硫富瓦烯和几种受电子富勒烯组成的电子给体-受体轭合物的设计、氧化还原电势、激发态能量和自由基离子对态能量。为此，我们根据电荷分离和电荷复合动力学，将空富勒烯 C₆₀与两种内包金属富勒烯（开壳层 La@C₈₂和闭壳层 La₂@C₈₀）进行了对比。
