膦烯对比亚磷烯：羰基修饰卡宾→PPh 加合物中 P-C 键的性质。
Phosphaalkene vs. phosphinidene: the nature of the P-C bond in carbonyl-decorated carbene → PPh adducts.
机构信息
Department of Chemistry and Biochemistry, Texas State University, San Marcos, TX 78666, USA.
出版信息
Chem Commun (Camb). 2014 Jan 7;50(2):162-4. doi: 10.1039/c3cc45134h.
PMID:23925541
Abstract
Treatment of dichlorophenylphosphine with two equivalents of carbonyl-decorated carbenes results in a two-electron reduction of the phosphorus centre concomitant with carbene oxidation to afford novel phosphaalkenes as confirmed via crystallographic, spectroscopic, and DFT analyses.
摘要
用两当量的羰基修饰卡宾处理二氯苯基膦，导致磷中心发生两电子还原，同时卡宾氧化生成新型的膦烯，通过晶体学、光谱学和 DFT 分析得到证实。
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