两个包含预先设计的配位纳米笼的二维金属-杯芳烃聚集体。
Two 2D metal-calixarene aggregates incorporating pre-designed coordination nanocages.
机构信息
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China.
出版信息
Chem Commun (Camb). 2013 Sep 25;49(74):8211-3. doi: 10.1039/c3cc42259c.
PMID:23926593
Abstract
Two 2D metal-calixarene aggregates were designed and assembled by M4-TC4A (M = Fe, Co; TC4A = p-tert-butylthiacalix[4]arene) SBUs and {MCl2} units with isonicotinic acid molecules, which presents a possible way to build the extended metal-calixarene assemblies incorporating pre-designed nanocages using multifunctional linkers.
摘要
两个 2D 金属-杯芳烃聚集体是通过 M4-TC4A（M = Fe，Co；TC4A = p-叔丁基硫代杯[4]芳烃） SBUs 和{ MCl2}单元与异烟酸分子设计和组装的，这为使用多功能连接物构建包含预设计纳米笼的扩展金属-杯芳烃组装体提供了一种可能的方法。
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