Laboratory of Bioinorganic Chemistry, Chemistry Department, University of Crete, PO Box 2208, 71003 Heraklion, Crete, Greece.
Chem Commun (Camb). 2014 Jan 18;50(5):521-3. doi: 10.1039/c3cc45025b. Epub 2013 Aug 12.
A combination of noble-metal free components, a water soluble porphyrin photosensitizer zinc meso-tetrakis(1-methylpyridinium-4-yl)porphyrin chloride [ZnTMPyP(4+)]Cl4 (1) with cobaloxime complex [Co(III)(dmgH)2(py)Cl] (2) as a catalyst, creates an efficient system for photochemical hydrogen production acting under visible light with 280 TONs. This is the first example of a water soluble porphyrin acting as a photosensitizer for cobaloxime catalysed H2 production.
一种由贵金属自由组件、水溶性卟啉光敏剂锌中四（1-甲基吡啶-4-基）卟啉四氯盐[ZnTMPyP（4+）]Cl4（1）和钴肟配合物[Co（III）（dmgH）2（py）Cl]（2）作为催化剂组成的高效体系，在可见光下进行光催化制氢，产氢量达到 280 个TONs。这是首例水溶性卟啉作为钴肟催化 H2 产生的光敏剂的实例。
