Department of Chemistry, Bar-Ilan University, Ramat Gan, 52 900, Israel.
Dalton Trans. 2013 Oct 7;42(37):13323-6. doi: 10.1039/c3dt51543e. Epub 2013 Aug 12.
The one-electron oxidation of the dianionic diamido-diphenoxo Ni(II) complexes involving H-bonding (1(2-)), or not (2(2-)), yields the corresponding Ni(III) species; the formation, stability and electronic structures of which are affected by the H-bonding interactions.
二胺二氧代二价镍配合物(1(2-))通过氢键(1(2-))或不通过氢键(2(2-))的单电子氧化生成相应的三价镍物种;氢键相互作用影响了这些镍物种的形成、稳定性和电子结构。