Department of Chemistry, ZJU-NHU United R&D Center, Zhejiang University, Hangzhou 310027 (P.R. China).
Angew Chem Int Ed Engl. 2013 Sep 27;52(40):10620-4. doi: 10.1002/anie.201305234. Epub 2013 Aug 12.
You can have your cake and eat it too: A "dual-tuning" strategy for improving the capture of SO2 was developed by introducing electron-withdrawing sites on the anions to produce several kinds of functionalized ionic liquids. Those functionalized with a halogen group exhibited improved performance over their non-halogenated counterparts, leading to highly efficient and reversible capture.
通过在阴离子上引入吸电子基团来开发一种“双重调谐”策略,以产生多种功能化离子液体。那些带有卤素基团的功能化离子液体的性能优于未带卤素基团的离子液体,从而实现了高效、可重复的捕获。