8-氨基喹啉：在金属催化的 C-H 键直接官能化中强有力的导向基团。
8-Aminoquinoline: a powerful directing group in metal-catalyzed direct functionalization of C-H bonds.
机构信息
Eco-Efficient Products & Processes Laboratory (E2P2L) Solvay/CNRS UMI 3464, Solvay Research & Innovation Center Shanghai, 3966 Jindu Road, Xinzhuang Industrial Zone, Shanghai 201108 (P. R. China) http://www.solvay.com.
出版信息
Angew Chem Int Ed Engl. 2013 Sep 16;52(38):9896-8. doi: 10.1002/anie.201303556. Epub 2013 Aug 12.
Chelate me if you can: Over the last decade, strategies for the functionalization of both C(sp2)-H and C(sp3)-H bonds have witnessed an increasing use of a simple, yet powerful directing group, 8-aminoquinoline (in blue). This auxiliary is very efficient in a wide range of metal-mediated reactions, and can be readily removed to afford the desired carboxylic acids or corresponding derivatives.
如果你能螯合我
在过去的十年中，用于功能化 C(sp2)-H 和 C(sp3)-H 键的策略越来越多地使用了一种简单而强大的导向基团，即 8-氨基喹啉（蓝色）。这种助剂在广泛的金属介导反应中非常有效，并且可以很容易地去除以获得所需的羧酸或相应的衍生物。
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