硝酸盐阴离子模板组装[2]轮烷，用于在水溶剂混合物中选择性识别硝酸盐。
Nitrate anion templated assembly of a [2]rotaxane for selective nitrate recognition in aqueous solvent mixtures.
机构信息
Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, OX1 3TA, UK.
出版信息
Chem Commun (Camb). 2013 Oct 7;49(77):8608-10. doi: 10.1039/c3cc45342a.
PMID:23949001
Abstract
The first nitrate anion templated assembly of an interlocked molecular architecture is demonstrated through the preparation of a [2]rotaxane. Removal of the discrete nitrate anion template from the [2]rotaxane reveals an interlocked host system capable of strong and selective recognition of nitrate, in aqueous-organic solvent mixtures, over a range of more basic mono-charged oxoanions.
摘要
首例硝阴离子模板化的分子互锁组装结构通过制备[2]轮烷得到了证明。从[2]轮烷中去除离散的硝阴离子模板，揭示了一种互锁主体系统，该系统能够在水-有机溶剂混合物中，对一系列更碱性的单价含氧阴离子进行强选择性识别。
Zotero 插件