State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling ling Lu, Shanghai 200032, P. R. China.
Chem Commun (Camb). 2013 Oct 7;49(77):8650-2. doi: 10.1039/c3cc44757j.
Gold-catalyzed cycloisomerization of 1,7-diyn-3,6-bis(propargyl carbonate)s leads to a highly efficient and diastereoselective synthesis of functionalized naphtho[b]cyclobutenes. A cascade sequence involving gold-catalyzed double 3,3-rearrangement, 6π-electrocyclic reaction and a decarbonylative cyclization was proposed for this reaction.
金催化的 1,7-二炔-3,6-双（丙炔碳酸酯）环异构化反应导致功能化萘并[b]环丁烯的高效和立体选择性合成。该反应提出了一个涉及金催化的双重 3,3-重排、6π-电环化反应和脱羰环化的级联序列。
