Department of Chemistry, M V Lomonosov Moscow State University, Moscow 119991, Russia.
J Phys Chem A. 2013 Aug 29;117(34):8184-8. doi: 10.1021/jp403174u. Epub 2013 Aug 19.
Formation of the SiP radical through radiative association of Si((3)P) and P((4)S) atoms is studied using classical and quantum dynamics. Rate coefficients for formation in the two lowest doublet states and the two lowest quartet states are calculated for T = 10-20,000 K. Breit-Wigner theory is used to properly account for contribution from quantum mechanical resonances.
通过 Si((3)P) 和 P((4)S) 原子的辐射缔合形成 SiP 自由基的过程，使用经典和量子动力学进行了研究。在 T = 10-20,000 K 的情况下，计算了在两个最低双重态和两个最低四重态中形成的速率系数。使用 Breit-Wigner 理论正确地考虑了量子力学共振的贡献。
