手性α-羟基酮与芳胺的催化对映选择性 Amadori-Heyns 重排：光学活性α-芳氨基酮的合成。
Catalytic enantioselective Amadori-Heyns rearrangement of racemic α-hydroxy ketones with arylamines: synthesis of optically active α-arylamino ketones.
机构信息
Dipartimento di Scienze Chimiche e Geologiche, Università degli studi di Cagliari, Complesso Universitario di Monserrato, S.S. 554, Bivio per Sestu, I-09042, Monserrato, Cagliari, Italy.
出版信息
Chem Commun (Camb). 2013 Oct 9;49(78):8812-4. doi: 10.1039/c3cc45278f.
PMID:23958743
Abstract
A novel synthesis of optically active α-arylamino ketones through an organocatalytic enantioselective Amadori-Heyns rearrangement is described.
摘要
通过有机催化的对映选择性 Amadori-Heyns 重排反应，合成了具有光学活性的α-芳基氨基酮。
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