基于 TTFV 的分子夹和大环作为富勒烯的受体。
TTFV-based molecular tweezers and macrocycles as receptors for fullerenes.
机构信息
Department of Chemistry, Memorial University, St. John's, NL, Canada A1B 3X7.
出版信息
Org Lett. 2013 Sep 6;15(17):4532-5. doi: 10.1021/ol402093a. Epub 2013 Aug 21.
PMID:23964798
Abstract
Hybrids of tetrathiafulvalene vinylogues (TTFVs) and planar arenes were synthesized via the click reaction to form tweezer-like and macrocyclic structures. These compounds were investigated as receptors for fullerenes (C60 and C70) by UV-vis absorption and fluorescence spectroscopy.
摘要
通过点击反应合成了四硫富瓦烯乙烯基类似物（TTFVs）和平面芳烃的混合物，形成了镊子状和大环结构。通过紫外可见吸收光谱和荧光光谱研究了这些化合物作为富勒烯（C60 和 C70）受体的性能。
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