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共轭聚合物/纳米粒子纳米复合材料用于高效实时挥发性有机化合物传感器。

Conjugated polymer/nanoparticles nanocomposites for high efficient and real-time volatile organic compounds sensors.

机构信息

Department of Materials Science and Engineering, National Taiwan University , Taipei 106-17, Taiwan.

出版信息

Anal Chem. 2013 Oct 1;85(19):9305-11. doi: 10.1021/ac402052h. Epub 2013 Sep 12.

Abstract

The present work demonstrates a high efficient and low cost volatile organic compounds (VOCs) sensor. Nowadays, VOCs, which are typically toxic, explosive, flammable, and an environmental hazard, are extensively used in R&D laboratories and industrial productions. Real-time and accurately monitoring the presence of harmful VOC during the usage, storage, or transport of VOCs is extremely important which protects humans and the environment from exposure in case of an accident and leakage of VOCs. The present work utilizes conducting polymer/nanoparticles blends to sense various VOCs by detecting the variation of optical properties. The novel sensor features high sensitivity, high accuracy, quick response, and very low cost. Furthermore, it is easy to fabricate into a sensing chip and can be equipped anywhere such as a laboratory or a factory where the VOCs are either used or produced and on each joint between transporting pipes or each switch of VOC storage tanks. Real-time sensing is achievable on the basis of the instant response to VOC concentrations of explosive limits. Therefore, an alarm can be delivered within a few minutes for in time remedies. This research starts from investigating fundamental properties, processing adjustments, and a performance test and finally extends to real device fabrication that practically performs the sensing capability. The demonstrated results significantly advance the current sensor technology and are promising in commercial validity in the near future for human and environmental safety concerns against hazardous VOCs.

摘要

本工作展示了一种高效且低成本的挥发性有机化合物(VOC)传感器。如今,VOC 广泛应用于研发实验室和工业生产中,通常具有毒性、爆炸性、易燃性和对环境有害等特点。在使用、储存或运输 VOC 期间,实时准确地监测有害 VOC 的存在非常重要,这可以防止人类和环境在 VOC 泄漏或事故发生时暴露于其中。本工作利用导电聚合物/纳米粒子混合物通过检测光学性质的变化来感测各种 VOC。新型传感器具有灵敏度高、精度高、响应快、成本低等特点。此外,它易于制成传感芯片,并可安装在使用或生产 VOC 的实验室或工厂,以及输送管道的每个接头或 VOC 储罐的每个开关处。基于对爆炸极限的 VOC 浓度的即时响应,可以实现实时感测。因此,可以在几分钟内发出警报,以便及时采取补救措施。本研究从调查基本特性、处理调整和性能测试开始,最终扩展到实际设备制造,实际展示了传感能力。所展示的结果显著推进了当前的传感器技术,并有望在不久的将来在商业有效性方面对人类和环境安全产生影响,以应对危险 VOC。

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