• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

用柱层析净化法清除农药残留提取物中纯化硅胶的活化和标准化。

Activation and standardization of purified silica gel for column chromatographic cleanup of pesticide residue extracts.

机构信息

Department of Entomology, Kansas State University, Manhattan, Kansas.

出版信息

Bull Environ Contam Toxicol. 1969 Mar;4(2):120-7. doi: 10.1007/BF01558425.

DOI:10.1007/BF01558425
PMID:23989232
Abstract

Activation and standardization studies have been conducted with high purity grades 950 and 923 silica gel to obtain an effective adsorbent for cleanup of pesticide residue extracts. Activation of silica gel at 130°C or 300°C for a 2-hr period was very satisfactory for separating pesticides from biological materials with high recovery of pesticides. No gain in the activity of the adsorbent resulted from prolonging heat treatment beyond the 2-hr period. It was also found that the activity of the silica gel was not affected by storing it in an air-tight container for as long as 60 days.

摘要

已对高纯 950 和 923 硅胶进行了活化和标准化研究,以获得一种有效的农药残留提取物净化用吸附剂。硅胶在 130°C 或 300°C 下活化 2 小时,非常有利于从生物材料中分离农药,且农药回收率很高。延长热处理时间超过 2 小时并不会增加吸附剂的活性。研究还发现,硅胶的活性在密封容器中储存长达 60 天也不会受到影响。

相似文献

1
Activation and standardization of purified silica gel for column chromatographic cleanup of pesticide residue extracts.用柱层析净化法清除农药残留提取物中纯化硅胶的活化和标准化。
Bull Environ Contam Toxicol. 1969 Mar;4(2):120-7. doi: 10.1007/BF01558425.
2
Determination of nitrogen- and phosphorus-containing pesticide residues in vegetables by gas chromatography with nitrogen-phosphorus and flame photometric detection after gel permeation chromatography and a two-step minicolumn cleanup.凝胶渗透色谱和两步微型柱净化后,采用氮磷检测和火焰光度检测气相色谱法测定蔬菜中含氮和含磷农药残留量
J AOAC Int. 2003 Nov-Dec;86(6):1241-51.
3
Ambient air sampling for tritium--determination of breakthrough volumes and collection efficiencies for silica gel adsorbent.用于氚的环境空气采样——硅胶吸附剂的穿透体积和收集效率的测定
Health Phys. 1997 Mar;72(3):397-407. doi: 10.1097/00004032-199703000-00007.
4
Automated gel permeation chromatographic cleanup of animal and plant extracts for pesticide residue determination.用于农药残留测定的动植物提取物的自动凝胶渗透色谱净化法。
J Assoc Off Anal Chem. 1976 Jan;59(1):174-87.
5
A rapid micromethod of sample cleanup for gas chromatographic analysis of insecticidal residues in plant, animal, soil, and surface and ground water extracts.一种快速的样品净化微方法,用于气相色谱分析植物、动物、土壤以及地表水和地下水提取物中的杀虫剂残留。
Bull Environ Contam Toxicol. 1967 Sep;2(5):264-73. doi: 10.1007/BF01684373.
6
Extraction and cleanup of organochlorine and organophosphorus pesticide residues in fats by supercritical fluid techniques.采用超临界流体技术提取和净化脂肪中的有机氯和有机磷农药残留。
J AOAC Int. 1997 May-Jun;80(3):639-46.
7
Development of an Automated Column Solid-Phase Extraction Cleanup of QuEChERS Extracts, Using a Zirconia-Based Sorbent, for Pesticide Residue Analyses by LC-MS/MS.采用基于氧化锆的吸附剂,开发 QuEChERS 提取物的自动化柱固相萃取净化方法,用于 LC-MS/MS 分析农药残留。
J Agric Food Chem. 2015 Jun 3;63(21):5107-19. doi: 10.1021/jf505539e. Epub 2015 Feb 23.
8
[Evaluation of New Cleanup Agents for Analysis of Pesticide Residues in Tea].[用于茶叶中农药残留分析的新型净化剂评估]
Shokuhin Eiseigaku Zasshi. 2017;58(3):155-159. doi: 10.3358/shokueishi.58.155.
9
The comparison of dispersive solid phase extraction and multi-plug filtration cleanup method based on multi-walled carbon nanotubes for pesticides multi-residue analysis by liquid chromatography tandem mass spectrometry.基于多壁碳纳米管的分散固相萃取和多塞过滤净化方法用于液相色谱串联质谱法农药多残留分析的比较。
J Chromatogr A. 2015 Mar 13;1385:1-11. doi: 10.1016/j.chroma.2015.01.066. Epub 2015 Jan 28.
10
Automated multi-filtration cleanup with nitrogen-enriched activated carbon material as pesticide multi-residue analysis method in representative crop commodities.以富氮活性炭材料进行自动多过滤净化作为代表性农作物商品中农药多残留分析方法
J Chromatogr A. 2017 Sep 15;1515:62-68. doi: 10.1016/j.chroma.2017.08.009. Epub 2017 Aug 5.

引用本文的文献

1
A feasibility study of miniature silica gel columns for the separation of some polychlorinated biphenyls, DDT, and analogs.用于分离某些多氯联苯、滴滴涕及其类似物的微型硅胶柱可行性研究。
Bull Environ Contam Toxicol. 1974 Dec;12(6):710-6. doi: 10.1007/BF01685919.
2
A multiclass, multiresidue analytical method for determining pesticide residues in air.一种用于测定空气中农药残留的多类别、多残留分析方法。
Arch Environ Contam Toxicol. 1975;3(1):55-71. doi: 10.1007/BF02221131.

本文引用的文献

1
Application of the rapid micromethod of sample cleanup for gas chromatographic analysis of common organic pesticides in ground water, soil, plant and animal extracts.快速微量样品净化方法在气相色谱分析地下水、土壤、植物和动物提取物中常见有机农药的应用。
Bull Environ Contam Toxicol. 1968 Mar;3(2):65-70. doi: 10.1007/BF01723728.
2
A rapid micromethod of sample cleanup for gas chromatographic analysis of insecticidal residues in plant, animal, soil, and surface and ground water extracts.一种快速的样品净化微方法,用于气相色谱分析植物、动物、土壤以及地表水和地下水提取物中的杀虫剂残留。
Bull Environ Contam Toxicol. 1967 Sep;2(5):264-73. doi: 10.1007/BF01684373.
3
The effect of heat-treatment on the sorption-desorption hysteresis characteristics of silica gel.
热处理对硅胶吸附-解吸滞后特性的影响。
J Phys Colloid Chem. 1947 Jan;51(1):333-59. doi: 10.1021/j150451a026.