Departamento de Química Orgánica, Área Química y Microbiología de Alimentos, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, C1428EGA Buenos Aires, Argentina.
Food Chem. 2013 Dec 15;141(4):3790-5. doi: 10.1016/j.foodchem.2013.06.093. Epub 2013 Jun 29.
The kinetics of Maillard reaction in lactose-hydrolysed skim milk powder and related systems containing carbohydrate mixtures were analysed. The effect of the increase of water activity and temperature during storage of the commercial product was also evaluated. In systems with two and three carbohydrates, a marked decrease of the reaction rate was observed when monosaccharides were partially replaced by lactose, notwithstanding the fact that the former still remained in a higher proportion than lysine. The rate of available lysine loss in lactose-hydrolysed milk was mostly affected by the presence of galactose. The reaction rate constants at aw 0.52 and at 37 and 50 °C were higher than at aw 0.33. However, no significant differences were observed at 60 °C. Temperature is the most important factor to be controlled in order to minimise nutritional deterioration during storage.
分析了乳糖水解脱脂奶粉及含碳水化合物混合物的相关体系中美拉德反应的动力学。还评估了商业产品在储存过程中水分活度和温度升高的影响。在含有两种和三种碳水化合物的体系中,当部分单糖被乳糖取代时,反应速率明显下降,尽管前者仍保持比赖氨酸更高的比例。乳糖水解乳中游离赖氨酸损失的速率主要受半乳糖的存在影响。在水分活度为 0.52 以及在 37 和 50°C 时的反应速率常数高于在水分活度为 0.33 时的值。然而,在 60°C 时没有观察到显著差异。为了在储存过程中最小化营养恶化,温度是需要控制的最重要因素。