Institut des Sciences Analytique de Lyon, UMR 5280, Université Claude Bernard, Lyon 1, 69622 Villeurbanne, France.
Chemosphere. 2014 Jan;95:41-9. doi: 10.1016/j.chemosphere.2013.08.010. Epub 2013 Sep 4.
Aqueous solubility and vapor pressures of 1,2,3,4-dibenzanthracene and 1,2,5,6-dibenzanthracene were determined using dynamic saturation methods. For the two isomers, aqueous solubility is in the range between 10(-10) and 10(-2) in molar fraction corresponding to temperature between 298.15 and 338.15K. Vapor pressures of the pure solutes range from 10(-5) to 80 Pa. Prior to the study of the two dibenzanthracenes and in order to check the experimental procedures, solubility of fluoranthene (between 298 and 338 K) and vapor pressures of phenanthrene and fluoranthene (between 300 and 470 K) were measured. From aqueous solubility data coupled with the vapor pressures of the pure solutes, partition coefficient air-water, KAW, and Henry's constant, KH, of environmental relevance were calculated.
采用动态饱和法测定了 1,2,3,4-二苯并蒽和 1,2,5,6-二苯并蒽的水溶解度和蒸气压。对于这两种异构体,水溶解度在摩尔分数为 10(-10) 到 10(-2) 之间,温度范围为 298.15 到 338.15K。纯溶质的蒸气压范围为 10(-5) 到 80 Pa。在研究这两种二苯并蒽之前,为了检查实验程序,还测量了荧蒽(298 到 338 K 之间)的溶解度,以及蒽和荧蒽(300 到 470 K 之间)的蒸气压。根据水溶解度数据和纯溶质的蒸气压,计算了环境相关的分配系数空气-水(KAW)和亨利常数(KH)。