Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University, Jinju 660-701 (Republic of Korea).
Chemistry. 2013 Oct 4;19(41):13638-45. doi: 10.1002/chem.201302633. Epub 2013 Sep 6.
The ratio is the key: On varying the molar ratio of the reactants, AgNO3 and tridentate m-L ligand, supramolecular isomers 1 and 2 comprising a 2D polymeric network were obtained. Conformational differences of m-L play a crucial role in the 2D network structures adopted for isomers 1 and 2.
改变反应物硝酸银和三齿配体 m-L 的摩尔比,可以得到包含二维聚合物网络的超分子异构体 1 和 2。m-L 的构象差异在异构体 1 和 2 所采用的二维网络结构中起着至关重要的作用。