具有缓冲形空腔的二维沸石咪唑骨架用于 CO2 吸附。
A two-dimensional zeolitic imidazolate framework with a cushion-shaped cavity for CO2 adsorption.
机构信息
Department of Chemical Engineering, Monash University, Clayton, Victoria 3800, Australia.
出版信息
Chem Commun (Camb). 2013 Oct 21;49(82):9500-2. doi: 10.1039/c3cc44342f.
PMID:24018656
Abstract
A new two-dimensional zeolitic imidazolate framework (named as ZIF-L) was synthesized in zinc salt and 2-methylimidazole (Hmim) aqueous solution at room temperature. ZIF-L (Zn(mim)2·(Hmim)1/2·(H2O)3/2 or C10H16N5O3/2Zn) has unique cushion-shaped cavities and leaf-like crystal morphology, and exhibits excellent CO2 adsorption properties.
摘要
一种新型二维沸石咪唑酯骨架（命名为 ZIF-L）在室温下的锌盐和 2-甲基咪唑（Hmim）水溶液中合成。ZIF-L（Zn(mim)2·(Hmim)1/2·(H2O)3/2 或 C10H16N5O3/2Zn）具有独特的缓冲形空腔和叶状晶体形态，并表现出优异的 CO2 吸附性能。
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