在[Pd(I)-Pd(I)]平台上实现室温 C-H 键活化。
Room temperature C-H bond activation on a [Pd(I)-Pd(I)] platform.
机构信息
Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India.
出版信息
Chem Commun (Camb). 2013 Oct 28;49(84):9764-6. doi: 10.1039/c3cc44493g.
PMID:24030737
Abstract
Heteroatom assisted C-H bond activation of 2-substituted naphthyridines with solvated Pd(I)2(CH3CN)6(BF4)2 provides bi- and trinuclear Pd(II) cyclometalated complexes, which provide valuable insight into potential intermediates in palladium catalyzed direct arylation reactions.
摘要
杂原子辅助的 2-取代的萘啶 C-H 键活化与溶剂化的 Pd(I)2(CH3CN)6(BF4)2 提供了双核和多核 Pd(II)环金属化配合物，这为钯催化的直接芳基化反应中的潜在中间体提供了有价值的见解。
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