Wisitsorasak Apiwat, Wolynes Peter G
Center for Theoretical Biological Physics, Rice University, Houston, Texas 77005, USA and Department of Physics & Astronomy, Rice University, Houston, Texas 77005, USA.
Phys Rev E Stat Nonlin Soft Matter Phys. 2013 Aug;88(2):022308. doi: 10.1103/PhysRevE.88.022308. Epub 2013 Aug 16.
In the context of the random first order transition theory we use an extended mode coupling theory of the glass transition that includes activated events to account for spatiotemporal structures in rejuvenating glasses. We numerically solve fluctuating dynamical equations for mobility and fictive temperature fields which capture both mobility generation through activated events and facilitation effects. Upon rejuvenating, a source of high mobility at a glass surface initiates a growth front of mobility which propagates into the unstable low mobility region. The speed of the front quantitatively agrees with experiments on the rejuvenation of ultrastable glasses, which "melt" from their surface.
在随机一阶转变理论的背景下,我们使用玻璃转变的扩展模式耦合理论,该理论包括活化事件以解释老化玻璃中的时空结构。我们通过数值方法求解迁移率和虚拟温度场的波动动力学方程,这些方程捕捉了通过活化事件产生的迁移率和促进效应。老化时,玻璃表面高迁移率的源头引发迁移率增长前沿,该前沿传播到不稳定的低迁移率区域。前沿速度与超稳定玻璃从其表面“熔化”的老化实验结果在定量上相符。