Lubchenko V, Wolynes P G
Department of Chemistry and Biochemistry, University of California at San Diego, La Jolla, California 92093-0371, USA.
Phys Rev Lett. 2001 Nov 5;87(19):195901. doi: 10.1103/PhysRevLett.87.195901. Epub 2001 Oct 19.
Several puzzling regularities concerning the low temperature excitations of glasses are quantitatively explained by quantizing domain wall motions of the random first order glass transition theory. The density of excitations agrees with experiment and scales with the size of a dynamically coherent region at T(g), being about 200 molecules. The phonon coupling depends on the Lindemann ratio for vitrification yielding the observed universal relation l/lambda approximately 150 between phonon wavelength lambda and mean free path l. Multilevel behavior is predicted to occur in the temperature range of the thermal conductivity plateau.
关于玻璃低温激发的几个令人困惑的规律,通过对随机一级玻璃转变理论中的畴壁运动进行量子化得到了定量解释。激发密度与实验结果相符,并且与T(g) 时动态相干区域的大小成比例,该区域约为200个分子。声子耦合取决于玻璃化的林德曼比,从而得出声子波长λ与平均自由程l之间观测到的普遍关系l/λ≈150。预计在热导率平台的温度范围内会出现多级行为。