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三元和四元盘状溶致液晶中的动态光散射和粘度测量:用盐调节回流

Dynamic light scattering and viscosity measurements in a ternary and quaternary discotic lyotropic nematic liquid crystal: tuning the backflow with salt.

作者信息

Risi C L S, Figueiredo Neto A M, Akpinar E, Santos M B Lacerda

机构信息

Instituto de Física, Universidade de São Paulo, Caixa Postal 66318, 05314-970 São Paulo, São Paulo, Brazil.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2013 Aug;88(2):022506. doi: 10.1103/PhysRevE.88.022506. Epub 2013 Aug 26.

Abstract

Using a dynamic light scattering technique, we measure the damping rate of thermal fluctuations of the nematic director for the so-called disklike nematic N(D) phase of both the ternary lyotropic K-laurate-1-decanol-H(2)O system and the quaternary one of similar composition except for the addition of salt (K(2)SO(4)). By varying the scattering angle in suitable geometries and polarizations, we are able to measure the orientational diffusivities associated with the pure deformations of splay and twist. A previous study made in the N(D) phase of the same ternary system yielded a large deviation between the splay and twist diffusivities. The effect was then interpreted in terms of the anisotropy between their associated viscosities due to induced flows, or backflow. In the present work we observe a strong increase of the backflow as an effect of the added salt. In addition, we make auxiliary measurements of shear viscosity and magnetic instabilities, which help to characterize the effect of the salt in the orientational diffusivities as they are mixed quantities involving elastic constants and viscosity coefficients.

摘要

我们使用动态光散射技术,测量了三元溶致液晶月桂酸钾 - 1 - 癸醇 - H₂O 体系以及除添加盐(K₂SO₄)外成分相似的四元体系中所谓盘状向列相 N(D) 相中向列指向矢热涨落的阻尼率。通过在合适的几何结构和偏振中改变散射角,我们能够测量与展曲和扭曲纯形变相关的取向扩散率。先前在同一三元体系的 N(D) 相中的研究表明,展曲和扭曲扩散率之间存在很大偏差。该效应随后根据由于诱导流或回流导致的相关粘度之间的各向异性来解释。在本工作中,我们观察到作为添加盐的效应,回流显著增加。此外,我们对剪切粘度和磁不稳定性进行了辅助测量,这有助于表征盐在取向扩散率中的效应,因为它们是涉及弹性常数和粘度系数的混合量。

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