表面亚稳相引发成核和奥斯特瓦尔德熟化：一种简便的无氟过程，用于制备球形蓬松核/壳、蛋黄/壳和空心锐钛矿纳米结构。
Surface-metastable phase-initiated seeding and ostwald ripening: a facile fluorine-free process towards spherical fluffy core/shell, yolk/shell, and hollow anatase nanostructures.
机构信息
Particulate Fluids Processing Centre, School of Chemistry, The University of Melbourne, Victoria 3010 (Australia).
出版信息
Angew Chem Int Ed Engl. 2013 Oct 11;52(42):10986-91. doi: 10.1002/anie.201305819. Epub 2013 Aug 23.
PMID:24039077
Abstract
Versatile synthetic method: Monodisperse anatase microspheres with various complex morphologies have been synthesized by using a versatile fluorine-free solvothermal process in the presence of ammonia. Unambiguous evidence related to surface seeding and a subsequent hollowing process revealed an Ostwald ripening evolution process.
摘要
多功能合成方法
在氨存在下，通过一种通用的无氟溶剂热工艺，合成了具有各种复杂形貌的单分散锐钛矿微球。有关表面成核和随后的空心化过程的明确证据揭示了奥斯特瓦尔德熟化演变过程。
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