具有新型 {Re3Mo3S8} 核的杂核簇合物：直接合成、性质和 DFT 计算。
Heterometallic clusters with a new {Re3Mo3S8} core: direct synthesis, properties and DFT calculations.
机构信息
Nikolaev Institute of Inorganic Chemistry, 3, Acad. Lavrentiev Ave., Novosibirsk, 630090, Russia.
出版信息
Chem Commun (Camb). 2013 Nov 4;49(85):10019-21. doi: 10.1039/c3cc44643c.
PMID:24045787
Abstract
We report the direct facile high-temperature synthesis and investigation of heterometallic rhenium-molybdenum cluster K6[Re3Mo3S8(CN)4(CN)2/2] (1) with a new {Re3Mo3S8} core. Dissolution of polymeric compound 1 resulted in subsequent oxidation and formation of stable 23e paramagnetic anionic cluster complex Re3Mo3S8(CN)6.
摘要
我们报告了具有新型{Re3Mo3S8}核的同多金属铼-钼簇 K6[Re3Mo3S8(CN)4(CN)2/2]（1）的直接简便高温合成和研究。化合物 1 的溶解导致随后的氧化和稳定的 23e 顺磁阴离子簇配合物Re3Mo3S8(CN)6的形成。
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