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二氯双（吡啶 -2- 硒代 -κ(2)N,Se）锡（IV）

Dichloridobis(pyridine-2-seleno-lato-κ(2) N,Se)tin(IV).

作者信息

Mammadova Gunay Z, Ismaylova Sheyda R, Matsulevich Zhanna V, Osmanov Vladimir K, Borisov Alexander V, Khrustalev Victor N

机构信息

Baku State University, Z. Khalilov Street 23, Baku AZ-1148, Azerbaijan.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 8;69(Pt 7):m364-5. doi: 10.1107/S1600536813014657. eCollection 2013.

DOI:10.1107/S1600536813014657
PMID:24046550
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3772407/
Abstract

The title compound, [SnCl2(C5H4NSe)2], is the product of a reaction of 2,2'-dipyridyl diselenide with tin tetra-chloride. The mol-ecule is located about a twofold rotation axis. The coordination environment of the Sn(IV) atom is a distorted octa-hedron, with two bidentate 2-pyridine-seleno-late ligands inclined to each other at an angle of 83.96 (7)°. The two Sn-Cl and two Sn-N bonds are in cis configurations, while the two Sn-Se bonds of 2.5917 (3) Å are in a trans configuration, with an Se-Sn-Se angle of 157.988 (15)°. In the crystal, π-π inter-actions between the pyridine rings [centroid-to-centroid distance of 3.758 (3) Å] and weak inter-molecular C-H⋯Cl hydrogen bonds link the mol-ecules into chains along the c axis.

摘要

标题化合物[SnCl₂(C₅H₄NSe)₂]是2,2'-二吡啶二硒化物与四氯化锡反应的产物。分子位于一个二重旋转轴上。Sn(IV)原子的配位环境是一个扭曲的八面体，两个双齿2-吡啶硒酸酯配体相互倾斜，夹角为83.96(7)°。两条Sn-Cl键和两条Sn-N键呈顺式构型，而两条键长为2.5917(3) Å的Sn-Se键呈反式构型，Se-Sn-Se角为157.988(15)°。在晶体中，吡啶环之间的π-π相互作用[质心间距为3.758(3) Å]和弱分子间C-H⋯Cl氢键将分子沿c轴连接成链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/424d/3772407/19fabd6c7fcb/e-69-0m364-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/424d/3772407/a1b288b8c48c/e-69-0m364-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/424d/3772407/87cc2dc55a41/e-69-0m364-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/424d/3772407/19fabd6c7fcb/e-69-0m364-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/424d/3772407/a1b288b8c48c/e-69-0m364-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/424d/3772407/87cc2dc55a41/e-69-0m364-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/424d/3772407/19fabd6c7fcb/e-69-0m364-fig3.jpg

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本文引用的文献

1
Dichloridobis(pyridine-2-thiol-ato-κ²N,S)tin(IV): a new polymorph.二氯双（吡啶-2-硫醇根合-κ²N,S）锡（IV）：一种新的多晶型物。
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m875-6. doi: 10.1107/S1600536812024026. Epub 2012 Jun 13.
2
Bis(3-methyl-2-pyridyl)ditelluride and pyridyl tellurolate complexes of zinc, cadmium, mercury: Synthesis, characterization and their conversion to metal telluride nanoparticles.双（3-甲基-2-吡啶基）二碲化物和吡啶基碲化物配合物的锌、镉、汞：合成、表征及其转化为金属碲化物纳米粒子。
Dalton Trans. 2009 Oct 21(39):8378-85. doi: 10.1039/b910466f. Epub 2009 Aug 24.
3
A short history of SHELX.
SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
4
Coordination Chemistry of 2,2'-Dipyridyl Diselenide: X-ray Crystal Structures of PySeSePy, [Zn(PySeSePy)Cl(2)], [(PySeSePy)Hg(C(6)F(5))(2)], [Mo(SePy)(2)(CO)(3)], [W(SePy)(2)(CO)(3)], and [Fe(SePy)(2)(CO)(2)] (PySeSePy = C(5)H(4)NSeSeC(5)H(4)N; SePy = [C(5)H(4)N(2-Se)-N,Se]).2,2'-二吡啶二硒醚的配位化学：PySeSePy、[Zn(PySeSePy)Cl₂]、[(PySeSePy)Hg(C₆F₅)₂]、[Mo(SePy)₂(CO)₃]、[W(SePy)₂(CO)₃]和[Fe(SePy)₂(CO)₂]的X射线晶体结构（PySeSePy = C₅H₄NSeSeC₅H₄N；SePy = [C₅H₄N(2-Se)-N,Se]）。
Inorg Chem. 1996 Jun 19;35(13):3990-3997. doi: 10.1021/ic951454d.
5
Pyridineselenolate Complexes of Tin and Lead: Sn(2-SeNC(5)H(4))(2), Sn(2-SeNC(5)H(4))(4), Pb(2-SeNC(5)H(4))(2), and Pb(3-Me(3)Si-2-SeNC(5)H(3))(2). Volatile CVD Precursors to Group IV-Group VI Semiconductors.锡和铅的吡啶硒酸盐配合物：Sn(2-SeNC(5)H(4))(2)、Sn(2-SeNC(5)H(4))(4)、Pb(2-SeNC(5)H(4))(2)和Pb(3-Me(3)Si-2-SeNC(5)H(3))(2)。IV族- VI族半导体的挥发性化学气相沉积前驱体
Inorg Chem. 1996 Jan 17;35(2):342-346. doi: 10.1021/ic9507326.
6
The novel crystal and molecular structure of bis[bis(2-pyridyl) disulfide]copper(I) perchlorate.
J Am Chem Soc. 1976 Nov 24;98(24):7569-78. doi: 10.1021/ja00440a021.